Oxidation of o-chloro and o-hydroxy benzyl alcohols catalyzed by copper (II) tetraphenylporphyrin nanoparticles synthesized by mixed solvent method


Rahmatollah Rahimi, Ensieh Gholamrezapor, Mohammad Reza Naimi-Jamal, Mahboubeh Rabbani


Tetraphenylporphyrin (TPP) and copper tetraphenylporphyrin (CuTPP) were synthesized and characterized by IR, UV-Vis, 1HNMR and 13CNMR. The CuTPP nanoparticles were synthesized by sonication and mixed solvent methods. These nanoparticles were characterized by AFM and SEM images and UV-Vis spectra. The catalytic activity of nanoparticles was investigated by oxidation of o-cholorond o-hydroxy benzyl alcohols in presence of molecular oxygen and isobutyraldehyde. The yields of oxidation of o-hydroxy benzyl alcohol by the two catalysts, CuTPP NPs and CuTPP, are 96.5% and ~ 2%, respectively. It is very obvious that the oxidation at the presence of CuTPP NPs catalyst is very high but selectivity for both reactants is 100%.


DOI: j.ccl.2012.6.003

Keywords: Copper (II) tetraphenylporphyrin Nanoparticles ,Molecular oxygen ,Benzyl alcohol ,Oxidation

How to cite this paper:

Rahimi, R., Gholamrezapor, E., Naimi-Jamal, M., & Rabbani, M. (2012). Oxidation of o-chloro and o-hydroxy benzyl alcohols catalyzed by copper (II) tetraphenylporphyrin nanoparticles synthesized by mixed solvent method.Current Chemistry Letters, 1(3), 101-108.


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